刘堂林,彭阳峰,赵红亮,童天中

• 1:华东理工大学化工学院

摘要(Abstract)：

为了从生产1-羟基苯并三氮唑的废水中去除邻硝基氯苯(OCNB)和邻硝基苯酚(ONP)，比较了6种大孔吸附树脂的吸附性能，筛选出吸附能力最优的大孔吸附树脂RD-100。静态吸附动力学研究显示，该树脂对OCNB和ONP的吸附动力学符合准一级模型，吸附过程符合Freundlich模型，即为多分子层吸附过程，对OCNB和ONP的最大理论吸附量分别为1 087.0 mg·g~(-1)和574.7 mg·g~(-1)。热力学研究表明，树脂吸附OCNB为吸热过程(ΔH=88.5 kJ·mol~(-1))，吸附ONP为放热过程(ΔH=-2.1 kJ·mol~(-1))，静态吸附循环再生6次后吸附容量仅衰减5.5%(OCNB)和6.2%(ONP)。单组分动态吸附的穿透点(C_t/C_0=5%)为420 min(ONP)和580 min(OCNB)。

关键词(KeyWords)： 大孔吸附树脂RD-100;邻硝基氯苯;邻硝基苯酚;吸附;废水处理

Abstract:

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基金项目(Foundation):

作者(Author): 刘堂林,彭阳峰,赵红亮,童天中

参考文献(References)：

• [1]CASTRO B, DORMOY J R, EVIN G, et al. Reactifs de couplage peptidique I(1)-l’hexafluorophosphate de benzotriazolyl Noxytrisdimethylamino phosphonium(B. O. P.)[J]. Tetrahedron Letters,1975,16(14):1219-1222.
• [2]唐鹏武，段正康，杨运泉.相转移催化合成1-羟基苯并三氮唑[J].精细化工中间体，2007(1):64-66.TANG W P, DUAN Z K, YANG Y Q. Synthesis of 1-hydroxy benzotriazole by phase-transfer catalysis[J]. Fine Chemical Intermediates,2007(1):64-66.
• [3]PARHAM H,SAEED S. Pre-concentration and determination of traces of nitrobenzene and 1,3-dinitrobenzene in water samples using anthracite adsorbent[J]. Journal of Industrial and Engineering Chemistry,2014,20(3):1003-1009.
• [4]DHARUPANEEDI S P, NATARAJ S K, NADAGOUDA M, et al. Membrane-based separation of potential emerging pollutants[J].Separation and Purification Technology,2019,210:850-866.
• [5]WANG Z M,XU S H,CAI J Z,et al. Perspective on photoelectrocatalytic removal of refractory organic pollutants in water systems[J].ACS ES&T Engineering,2022,2(6):1001-1014.
• [6]LUO Z R, YAO B, YANG X, et al. Novel insights into the adsorption of organic contaminants by biochar:A review[J].Chemosphere,2022,287:132113.
• [7]BELL J P, TSEZOS M. Removal of hazardous organic pollutants by adsorption on microbial biomass[J]. Water Science and Technology,1987,19(3/4):409-416.
• [8]SELLAOUI L, KEHILI M, LIMA E C, et al. Adsorption of phenol on microwave-assisted activated carbons:Modelling and interpretation[J]. Journal of Molecular Liquids,2019,274:309-314.
• [9]PHAM T H,LEE B K,KIM J. Improved adsorption properties of a nano zeolite adsorbent toward toxic nitrophenols[J]. Process Safety and Environmental Protection,2016,104:314-322.
• [10]SHAO L S,HUANG J H. Controllable synthesis of N-vinylimidazole-modified hyper-cross-linked resins and their efficient adsorption of p-nitrophenol and o-nitrophenol[J]. Journal of Colloid and Interface Science,2017,507:42-50.
• [11]KLUMPP E,CONTRERAS-ORTEGA C,KLAHRE P,et al. Sorption of 2,4-dichlorophenol on modified hydrotalcites[J]. Colloids and Surfaces A:Physicochemical and Engineering Aspects,2003,230(1/2/3):111-116.
• [12]CAO Y,ZHONG J,DAI Z. Multiple phenolic hydroxyl-modified hyper-crosslinked polymers and their efficient adsorptive removal of o-nitrophenol from water[J]. Industrial Engineering Chemistry Research,2023,62(37):15166-15175.
• [13]SALEH T A. Kinetic models and thermodynamics of adsorption processes:classification[M]. Interface Science and Technology.Elsevier,2022:65-97.
• [14]WU Y F, ZHANG L, MAO J W, et al. Kinetic and thermodynamic studies of sulforaphane adsorption on macroporous resin[J].Journal of Chromatography B,2016,1028:231-236.
• [15]KUANG W,LIU Y N,HUANG J. Phenol-modified hyper-cross-linked resins with almost all micro/mesopores and their adsorption to aniline[J]. Journal of Colloid and Interface Science,2017,487:31-37.
• [16]CHANG P B, ZHOU S Y, WANG T C, et al. Eco-friendly carbon nanotubes reinforced with sodium alginate/polyacrylic acid for enhanced adsorption of copper ions:kinetics,isotherm,and mechanism adsorption studies[J]. Molecules,2024,29(19):4518.
• [17]WANG Y, CAO Y C, ZONG J J, et al. Acetamido-functionalized hyper-crosslinked polymers for efficient removal of phenol in aqueous solution[J]. Separation and Purification Technology,2022,287:120566.