FCC三旋细颗粒凝结长大特性实验研究Growing characteristics of heterogeneous condensation of fine particles after FCC cyclone
王斯民,宋晨,王家瑞,孙利娟,张早校,文键
摘要(Abstract):
为进一步提高FCC三旋细颗粒脱除效率,基于蒸汽相变原理,在低过饱和度下进行了FCC三旋细颗粒相变长大特性的实验,并采用静电低压冲击器(EIPI+)测量相变长大前后颗粒粒径分布,研究了热水温度、颗粒初始浓度及烟气流量对颗粒相变长大的影响。结果表明:提高热水温度可显著促进颗粒长大;颗粒的初始浓度对其长大效果的影响因热水温度而异,具有一定不确定性;烟气流量增大会抑制颗粒长大。在最优的实验条件下,细颗粒的算术平均粒径由初始的1.35增大到6.76μm,已达FCC大三旋装置除尘的临界粒径,可进行工业分离。
关键词(KeyWords): 蒸汽相变;细颗粒;长大特性;除尘效率
基金项目(Foundation): 国家自然科学基金(51676146)
作者(Author): 王斯民,宋晨,王家瑞,孙利娟,张早校,文键
参考文献(References):
- [1]石零,陈红梅,杨成武.微细粉尘治理技术的研究进展[J].江汉大学学报(自然科学版),2013,41(2):40-46.SHI L,CHEN H M,YANG C W.Research progress of fine dust control technology[J].Journal of Jianghan University of Technology(Natural Science Edition),2013,41(2):40-46.
- [2]张翼飞,陈述卫,王兆斌.FCC三旋装置的技术现状与发展趋势[J].广东化工,2013,40(15):159-160,167.ZHANG Y F,CHEN S W,WANG Z B.Current technology situation and developing trend of the three-stage cyclone in FCCequipment[J].Guangdong Chemistry Industry,2013,40(15):159-160,167.
- [3]SCHAUER P J.Removal of submicron aerosol particles from moving gas stream[J].Industrial&Engineering Chemistry,1951,43(7):1532-1538.
- [4]BUNZ H,SCHOCK W.The behavior of highly concentrated aerosols in a condensing steam atmosphere[J].Journal of Aerosol Science,1976,10(2):197.
- [5]HEIDENREICH S,EBERT F.Condensational droplet growth as a preconditioning technique for the separation of submicron particles from gases[J].Chemical Engineering and Processing,1995,34(3):235-244.
- [6]LIU X Y.Heterogeneous nucleation or homogeneous nucleation?[J].Journal of Chemical Physics,2000,122(22):9949-9955.
- [7]LIU X Y.A new kinetic model for three-dimensional heterogeneous nucleation[J].Journal of Chemical Physics,1999,111(4):1628-1635.
- [8]SERGEY P F,WANG W N,MANABU S,et al.Vapor condensation on nanoparticles in the mixer of a particle size magnifier[J].International Journal of Heat and Mass Transfer,2006,50(11/12):2333-2338.
- [9]FAN F X,ZHANG S H,PENG Z B,et al.Numerical investigation of heterogeneous nucleation of water vapour on PM10 for particulate abatement[J].The Canadian Journal of Chemical Engineering,2019,97(4):930-939.
- [10]FAN F X,ZHANG S H,WANG W Y,et al.Numerical investigation of PM2.5 size enlargement by heterogeneous condensation for particulate abatement[J].Process Safety and Environmental Protection,2019,125(9):197-206.
- [11]SUN J J,LIU B,MCMURRY P,et al.A method to increase control efficiencies of wet scrubbers for submicron particles and particulate metals[J].Journal of the Air&Waste Management Association,1994,44(2):184-185.
- [12]ANDEREI B,HANNS R P,THOMAS W.Electro static charging of aerosol as a mechanism of gas cleaning from submicron particles[J].Filtration and Separation,2001,38(10):26-30.
- [13]DE JOANNON M,COZZOLINO G,CAVALIERE A,et al.Heterogeneous nucleation activation in a condensational scrubber for particulate abatement[J].Fuel Processing Technology,2012,107(3):113-118.
- [14]杨希刚,周磊,杨林军,等.水汽相变促进湿法脱硫净烟气中细颗粒物脱除的研究[J].高校化学工程学报,2019,33(2):496-504.YANG X G,ZHOU L,YANG L J,et al.Improvement of fine particle removal from desulfurized flue gas by heterogeneous condensation[J].Journal of Chemical Engineering of Chinese Universities,2019,33(2):496-504.
- [15]YU Y,ZHANG J,ZHONG H.Heterogeneous condensation of magnetized water vapor on fine SiO2 particles[J].Environmental Research,2019,169(2):173-179.
- [16]XU J C,YU Y,ZHANG J.Heterogeneous condensation on fine particles of water vapor in a moderated growth tube[J].Energy Procedia,2017,118(4):201-209.
- [17]ZHANG R,WU H,SI X D,et al.Improving the removal of fine particulate matter based on heterogeneous condensation in desulfurized flue gas[J].Fuels Processing Technology,2018,174(6):9-16.
- [18]周璐璐,张军,徐俊超,等.典型煤灰成分细颗粒物在过饱和水汽环境中的长大特性[J].燃料化学学报,2015,43(6):754-760.ZHOU L L,ZHANG J,XU J C,et al.The growth characteristics of fine particles of typical coal ash composition[J].Journal of Fuel Chemistry and Technology,2015,43(6):754-760.