改性橡胶木纤维素水凝胶的制备及其吸附性能研究Preparation and adsorption properties of modified rubber wood cellulose hydrogel
郑丁源,李梦扬,张显权,岳金权
摘要(Abstract):
为了解决橡胶木利用价值低的问题,尝试以改性橡胶木纤维素为基体制备水凝胶并应用于染料吸附以提高其利用价值。对橡胶木纤维素(PCF)进行羧甲基化改性,通过反相悬浮聚合法,制备水凝胶;以不同pH值的缓冲溶液为介质研究水凝胶的水溶胀性能;在不同浓度的缓冲溶液中研究水凝胶对罗丹明B(RhB)的吸附。结果表明,制备的球形水凝胶有一定的pH敏感性,并且对RhB的吸附性能良好,在pH为10、RhB浓度为1 200 mg×L~(-1)的缓冲溶液中,添加κ-卡拉胶的水凝胶对RhB的吸附容量为546.81 mg×g~(-1)。该球形水凝胶在染料吸附领域具有潜在应用价值。
关键词(KeyWords): 橡胶木;羧甲基纤维素;κ-卡拉胶;水凝胶;罗丹明B
基金项目(Foundation):
作者(Author): 郑丁源,李梦扬,张显权,岳金权
参考文献(References):
- [1]黄艳.世界橡胶木产销及其发展前景[J].中国热带农业, 2008(6):25-28.HUANG Y. Production and marketing of rubber wood in the world and its development prospect[J]. China Tropical Agriculture,2008(6):25-28.
- [2]周玉申,罗发民.橡胶木的特性与应用[J].广东林勘设计, 2002(4):13-18.ZHOU Y S, LUO F M. Characteristics and application of rubber wood[J]. Guangdong Forestry Surveying&Designing, 2002(4):13-18.
- [3]张金明,吕玉霞,罗楠,等.离子液体在纤维素化学中的应用研究进展[J].高分子通报, 2012(10):138-153.ZHANG J M, LV Y X, LUO N, et al. Application research process of ionic liquids in cellulose chemistry[J]. Polymer Bulletin,2011(10):138-153.
- [4]瞿冰,方亮晶,肖慧宁,等.分布合成羧甲基纤维素/聚丙烯酸甲酯pH敏感互穿网络水凝胶及其表征[J].高分子材料科学与工程, 2015, 31(4):17-20.QU B, FANG L J, XIAO H N, et al. Characterization of carboxymethylcellulose/poly(methyl acrylate)pH-sensitivity IPN hydrogel synthesized by fractional step method[J]. Polymer Materials Science&Engineering, 2015, 31(4):17-20.
- [5]林丹.基于纤维素/壳聚糖水凝胶的合成及其对亚甲基蓝染料吸附性能的研究[D].兰州:西北师范大学, 2016.LIN D. Synthesis of cellulose/chitosan-based hydrogels and its adsorption performance of methylene blue dye[D]. Lanzhou:Northwest Normal University, 2016.
- [6]邓树斌.多孔纤维素水凝胶微球的制备与性能研究[D].天津:天津大学, 2007.DENG S B. Studies on preparation and properties of porous HPMC gel beads[D]. Tianjin:Tianjin University, 2007.
- [7]朱立平.反相悬浮聚合制备功能聚合物微球[D].天津:天津大学, 2004.ZHU L P. Preparation of functional polymer micro-sphere by inverse suspension polymerization[D]. Tianjin:Tianjin University, 2004.
- [8] RODRIGUEZ N L G D. THIELEMANS W. Sisal cellulose whiskers reinforced polyvinyl acetate nanocomposites[J]. Cellulose,2006, 13(3):261-270.
- [9]罗文超,刘淑敏,黄惠华.改性竹笋纤维水凝胶的制备与表征及其对亚甲基蓝吸附性能研究[J].现代食品科技, 2015, 31(3):165-171.LUO W C, LI S H, HUANG H H. Preparation and characterization of modified bamboo cellulose hydrogel and analysis of its adsorption capacity to methylene blue[J]. Modern Food Science and Technology, 2015, 31(3):165-171.
- [10]彭彬,沈冲,孟琴. DA-P123水凝胶的溶胀因素及其用于去除溶液中的重金属离子[J].高校化学工程学报, 2017, 31(6):1426-1432.PENG B, SHEN C, MENG Q. Swelling factors of DA-P123 hydrogel and its application in heavy metal ions removal from aqueous solutions[J]. Journal of Chemical Engineering of Chinese Universities, 2017, 31(6):1426-1432.
- [11] WANG T X. ZHOU L Y. Analysis of Rhodamine B in Chinese wolfberry from market sale by HPLC[J]. Advanced Materials Research, 2014, 1010/1011/1012:826-829.
- [12]李瑞雪,毕建柱,孔振兴,等.利用蔗渣制备高取代度羧甲基纤维素钠的研究[J].甘蔗糖业, 2013(6):29-35.LI R X, BI J Z, KONG Z X, et al. Preparation of carboxymethyl cellulose with high-degree substitution from bagasse[J]. Sugarcane and Canesugar, 2013(6):29-35.
- [13]聂荣华,柳明珠.羧甲基纤维素钠水凝胶的制备及其生物降解性研究[J].功能高分子学报, 2003, 16(4):553-556.NIE R H, LI M Z. Preparation and bio-degradation properties of hydrogel from sodium carboxymethyl cellulose[J]. Journal of Functional Polymers, 2003, 16(4):553-556.
- [14] CHEN W S. YU H P. Individualization of cellulose nanofibers from wood using high-intensity ultrasonication combined with chemical pretreatments[J]. Carbohydrate Polymers, 2011, 83(4):1804-1811.
- [15] CHEN W S. YU H P. Isolation and characterization of cellulose nanofibers from four plant cellulose fibers using a chemicalultrasonic process s[J]. Cellulose, 2011, 18(2):433-442.
- [16] MACCARINI M. ATREI A. Interactions at the CMC/magnetite interface:Implications for the stability of aqueous dispersions and the magnetic properties of magnetite nanoparticles[J]. Colloids&Surfaces A Physicochemical&Engineering Aspects, 2014, 462:107-114.
- [17] CUBA-CHIEM L T. HUYNH L. In situ particle film ATR FTIR spectroscopy of carboxymethyl cellulose adsorption on talc:Binding mechanism, pH effects, and adsorption kinetics[J]. Langmuir the ASC Journal of Surfaces&Colloids, 2008, 24(15):8036-8044.
- [18]李延顺.壳聚糖交联温度和pH双重敏感水凝胶的合成和性质研究[D].青岛:青岛科技大学, 2010.LI Y S. Synthesis and characterization of temperature and pH dual-sensitive hydrogels cross-linked with chitosan[D]. Qingdao:Qingdao University of Science&Technology, 2010.
- [19]孟凡玲,罗亮,宁辉,等.κ-卡拉胶的研究进展[J].高分子通报, 2003(5):49-56.MENG F L, LUO L, NING H, et al. Advances in the research ofκ-carrageenan[J]. Polymer Bulletin, 2003(5):49-56.
- [20]晁国涛. pH敏感水凝胶的合成及性能研究[D].成都:四川大学, 2007.CHAO G T. Study on the synthesis and the property of pH-sensitive hydrogels[D]. Chengdu:Sichuan University, 2007.
- [21]石艳丽,张高奇,马敬红,等.羧甲基纤维素钠/聚(N-异丙基丙烯酰胺)半互穿网络水凝胶的制备及润胀性能[J].高分子材料科学与工程, 2005, 21(5):145-148.CHI Y L, ZHANG G Q, MA J H, et al. Preparation and performance characterization of pH/temperature-sensitive sodium carboxymethylcellulose/poly(N-sopropylacrylamide)semi-IPN hydrogels[J]. Polymer Materials Science&Engineering, 2005,21(5):145-148.
- [22]魏清渤,高楼军,付峰,等. pH响应PAAm-g-PEG/PVP半互穿网络水凝胶的制备以及润胀动力学[J].化工进展, 2012, 31(1):163-168.WEI Q B, GAO L J, FU F, et al. Preparation and swelling kinetics of PAAm-g-PEG/PVP pH-responsive semi-IPN hydrogels[J].Chemical Industry and Engineering Progress, 2012, 31(1):163-168.
- [23] YU J. YANG G G. Poly(acrylamide-co-acrylic acid)hydrogel induced by glow-discharge electrolysis plasma and its adsorption properties for cationic dyes[J]. Plasma Science&Technology, 2014, 16(8):767-776.
- [24]姚志鹏,张颖,王慧,等. CoFe204-活性炭磁性纳米复合材料吸附去除罗丹明B染料[J].西南大学学报(自然科学版), 2015,37(7):166-169.YAO Z P, ZHANG Y, WANG H, et al. Removal of Rhodamine B by an activated carbon-CoFe204 magnetic nanocomposite[J].Journal of Southwest University(Natural Science Edition), 2015, 37(7):166-169.
- [25] MITTAL H. MAITY A. Gum karaya based hydrogel nanocomposites for the effective removal of cationic dyes from aqueous solutions[J]. Applied Surface Science, 2016, 364:917-930.
- [26]俞洁,张海涛,陆泉芳,等.埃缕石/聚乙烯醇/丙烯酸水凝胶的表征及其对阳离子染料的吸附性能[J].化工进展, 2015, 34(4):1115-1121.YU J, ZHANG H T, LU Q F, et al. Characterization of polygorskite/poly(ethylene glycol)/acrylic acid hydrogel and its application as an adsorbent for cationic dyes[J]. Chemical Industry and Engineering Progress, 2015, 34(4):1115-1121.
- [27] YAN H. XIANG Z. Enhancement of Rhodamine B removal by modifying activated carbon developed from Lythrum Salicaria L. with pyruvic acid[J]. Colloids&Surfaces A Physicochemical&Engineering Aspects, 2016, 489:154-162.
- [28] GAD H M H. EL-SAYED A A. Activated carbon from agricultural by-products for the removal of Rhodamine-B from aqueous solution[J]. Journal of Hazardous Materials, 2009, 168(2):1070-1081.
- [29] TANG Y. HE T. Sorption behavior of methylene blue and Rhodamine B mixed dyes onto chitosan graft poly(acrylic acid-co-2-acrylamide-2-methyl propane sulfonic acid)hydrogel[J]. Advances in Polymer Technology, 2018, 37(7):2568-2578.
- [30] LIN T. YE C. Cobalt nanoparticles-embedded magnetic ordered mesoporous carbon for high effective adsorption of Rhodamine B[J].Applied Surface Science, 2014, 314(24):746-753.