顾佳欢,李坚,任强,汪称意,盛刚

• 1:江苏省环境友好高分子材料重点实验室常州大学材料科学与工程学院材料化学系
• 2:江苏欧密格光电科技股份有限公司

摘要(Abstract)：

通过无皂乳液聚合,制备了以聚丙烯酸丁酯(PBA)为核,聚乙烯基苯磺酸钠(PSSNa)为壳的核壳型聚乙烯基苯磺酸钠/聚丙烯酸丁酯(PSSNa/PBA),并以此为模板制备了核壳型聚3,4-二氧乙烯噻吩(PEDOT)水分散体,研究了核壳型模板对PEDOT水分散体结构和性能的影响。结果显示:通过透射电镜(TEM)表征,证明成功制备了核壳型模板PSSNa/PBA和具有核壳结构的聚3,4-二氧乙烯噻吩:聚乙烯基苯磺酸钠/聚丙烯酸丁酯(PEDOT:PSSNa/PBA)水分散体。聚合动力学研究表明,以核壳型PSSNa/PBA为模板时,EDOT的聚合速率加快。表面方块电阻测试表明,较PEDOT:PSSNa薄膜,PEDOT:PSSNa/PBA薄膜的方块电阻降低近16倍,说明核壳结构的模板可改善PEDOT薄膜的导电性。

关键词(KeyWords)： 聚3,4-二氧乙烯噻吩;聚乙烯基苯磺酸钠;聚丙烯酸丁酯;核壳结构;导电性;透明性

Abstract:

Keywords:

基金项目(Foundation):

作者(Author): 顾佳欢,李坚,任强,汪称意,盛刚

参考文献(References)：

• [1]Duraisamy N,Hong S J,Choi K H.Deposition and characterization of silver nanowires embedded PEDOT:PSS thin films via electrohydrodynamic atomization[J].Chemical Engineering Journal,2013,225(2):887894.
• [2]Ahlswede E,Muhleisen W,Wahinuddin B M W M,et al.Highly efficient organic solar cells with printable low-cost transparent contacts[J].Applied Physics Letters,2008,92(14):143307-143307-3.
• [3]Hong K,Yang S Y,Yang C,et al.Reducing the contact resistance in organic thin-film transistors by introducing a PEDOT:PSS hole-injection layer[J].Organic Electronics,2008,9(5):864-868.
• [4]Burroughes J H,Bradley D D C,Brown A R,et al.Light-emitting diodes based on conjugated polymers[J].Nature,1990,347(6299):539-541.
• [5]Wu C H,Don T M,Chiu W Y.Characterization and conversion determination of stable PEDOT latex nanoparticles synthesized by emulsion polymerization[J].Polymer,2011,52(6):1375-1384.
• [6]Alemu D,Wei H Y,Ho K C,et al.Highly conductive PEDOT:PSS electrode by simple film treatment with methanol for ITO-free polymer solar cells[J].Energy&Environmental Science,2012,5(5):9662-9671.
• [7]Zhou J,Anjum D H,Lubineau G,et al.Unraveling the order and disorder in poly(3,4-ethylenedioxythiophene)/poly(styrenesulfonate)nanofilms[J].Macromolecules,2015,48(16):5688-5696.
• [8]Chen H Y,Shen H P,Wu C H,et al.Core–shell composite latexes derived from PEDOT:PSS dispersion and the preparation of conductive,flexible and transparent films[J].Journal of Materials Chemistry C,2013,1(34):5351-5358.
• [9]Yin H E,Wu C H,Kuo K S,et al.Innovative elastic and flexible conductive PEDOT:PSS composite films prepared by introducing soft latexes[J].Journal of Materials Chemistry,2012,22(9):3800-3810.
• [10]Yin H E,Huang F H,Chiu W Y.Hydrophobic and flexible conductive films consisting of PEDOT:PSS-PBA/fluorine-modified silica and their performance in weather stability[J].Journal of Materials Chemistry,2012,22(28):14042-14051.
• [11]YIN Nian-wei(殷年伟),CHEN Ke-qiang(陈克强),KANG Wei(康维).Preparation of BA/St/AM copolymer latexes by ultrasonic soap-free emulsion polymerization(超声无皂乳液聚合制备BA/St/AM三元共聚物乳胶粒及其聚合机理研究)[J].Acta Polymerica Sinica(高分子学报),2006,2(21):253-257.
• [12]OUYANG Xin-ping(欧阳新平),TAN Chun-mei(谭春枚),QIU Xue-qing(邱学青),et al.Synthesis of water-souble styrene and styrene sulfonate copolymer and its dispersion and stable effect for suspension(水溶性苯乙烯-苯乙烯磺酸钠共聚物的合成及分散稳定性能研究)[J].Journal of Chemical Engineering of Chinese Universities(高校化学工程学报),2010,24(4):681-687.
• [13]Xia Y J,Sun K,Ouyang J Y.Highly conductive poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate)films treated with an amphiphilic fluoro compound as the transparent electrode of polymer solar cells[J].Energy&Environmental Science,2012,5(1):5325-5332.
• [14]Han Y K,Chang M Y,Li H Y,et al.In situ synthesis and deposition of conducting PEDOT:PSS nanospheres on ITO-free flexible substrates[J].Materials Letters,2014,117(1):146-149.
• [15]LIU Shu-ying(刘书英),LI Jian(李坚),LI Yu-ling(李玉玲).Synthesis and characterization of poly(3,4-ethylenedio-xythiophene)/poly(styrenesulfonate)-poly(ethylene glycol)aqueous dispersion(导电聚合物PEDOT/PSS-MPEG的制备及性能).Journal of Chemical Industry and Engineering(化工学报),2012,4(63):1321-1327.
• [16]GU Jia-huan(顾佳欢),GAO Shan(高山),YAO Yao(姚尧),et al.Synthesis and characterization of poly(3,4-ethylenedio-xythiophene):poly(styrenesulfonate)-poly(allyl ethylene glycol)(导电聚合物PEDOT:PSS-APEG水分散体的制备及性能研究)[J].Ion Exchange and Adsorption(离子交换与吸附),2015,31(1):88-96.