李红宾¹,石文英^1,2,杜启云³,訾兴晨¹

• 1:河南工程学院 纺织学院，河南 郑州 450007
• 2:河南工程学院 纺织新产品开发河南省工程实验室，河南 郑州 450007
• 3:天津工业大学 分离膜与膜过程国家重点实验室，天津 300387

摘要(Abstract)：

热驱动的膜蒸馏技术以其极高截留率和较温和操作条件成为膜分离领域的一个重要分支。相较于传统相转化分离膜，静电纺纳米纤维膜由纳米纤维网络组成，比表面积及孔隙率更高且为互相贯通的开孔结构，能显著减小蒸汽传质阻力，提高水通量，有效突破膜蒸馏技术通量低的限制。但特殊的静电纺丝工艺使得高通透的纳米纤维膜面临着更严重的机械稳定性恶化及膜污染问题。从静电纺纳米纤维膜材料、膜制备、膜结构、改性技术、膜污染及膜蒸馏应用等6方面对近些年膜蒸馏用静电纺纳米纤维膜进行综述，并对其在膜蒸馏应用中亟需深入研究的内容及前景进行展望。

关键词(KeyWords)： 膜蒸馏;纳米纤维膜;静电纺;疏水化;膜污染

Abstract:

Keywords:

基金项目(Foundation): 国家自然科学基金（51403052）；河南省科技攻关项目（182102210254）。

作者(Author): 李红宾¹,石文英^1,2,杜启云³,訾兴晨¹

参考文献(References)：

• [1] 张金赫, 李花, 沈驭臣, 等. 膜蒸馏海水淡化过程中的两相流强化实验研究[J]. 高校化学工程学报, 2018, 32(1):38-43. ZHANG J H, LI H, SHEN Y C, et al. Experimental investigation on two-phase flow enhancement of desalination processes via membrane distillation[J]. Journal of Chemical Engineering of Chinese Universities, 2018, 32(1):38-43.
  [2] LI X, GARCÍA-PAYOB M C, KHAYET M, et al. Superhydrophobic polysulfone/polydimethylsiloxane electrospun nanofibrous membranes for water desalination by direct contact membrane distillation[J]. Journal of Membrane Science, 2017, 542:308-319.
  [3] 凤权, 武丁胜, 桓珊, 等. 再生纤维素纳米纤维膜的制备及其蛋白质分离性能[J]. 纺织学报, 2016, 37(12):12-17. FENG Q, WU D S, HUAN S, et al. Preparation and protein separation properties of regenerated cellulose nanofiber membrane[J]. Journal of Textile Research, 2016, 37(12):12-17.
  [4] 陆培培, 许振良, 杨虎, 等. PFSA-PES-纳米颗粒复合纳米纤维的制备及催化性能[J]. 化工学报, 2013, 64(4):1466-1472. LU P P, XU Z L, YANG H, et al. Preparation of perfluorosulfonic acid-polyethersulfone-nanoparticles composite nanofibers and their catalytic properties[J]. CIESC Journal, 2013, 64(4):1466-1472.
  [5] FRANCIS L, GHAFFOUR N, ALSAADI A S, et al. PVDF hollow fiber and nanofiber membranes for fresh water reclamation using membrane distillation[J]. Journal of Materials Science, 2014, 49(5):2045-2053.
  [6] WANG P, TEOH M M, CHUNG T S. Morphological architecture of dual-layer hollow fiber for membrane distillation with higher desalination performance[J]. Water Research, 2011, 45(7):5489-5500.
  [7] BAGGER-JØRGENSEN R, MEYER A S, PINELO M, et al. Recovery of volatile fruit juice aroma compounds by membrane technology:Sweeping gas versus vacuum membrane distillation[J]. Innovative Food Science and Emerging Technologies, 2011, 12(3):388-397.
  [8] FARD A K, MANAWI Y M, RHADFI T, et al. Synoptic analysis of direct contact membrane distillation performance in Qatar:A case study[J]. Desalination, 2015, 360:97-107.
  [9] LU D P, LI P, XIAO W, et al. Simultaneous recovery and crystallization control of saline organic wastewater by membrane distillation crystallization[J]. AIChE Journal, 2017, 63(6):2187-2197.
  [10] WEN X, LI F Z, JIANG B, et al. Effect of surfactants on the treatment of radioactive laundry wastewater by direct contact membrane distillation[J]. Journal of Chemical Technology and Biotechnology, 2018, 93(8):2252-2261.
  [11] ZUO J, BONYADI S, CHUNG T S. Exploring the potential of commercial polyethylene membranes for desalination by membrane distillation[J]. Journal of Membrane Science, 2016, 497:239-247.
  [12] KOEMAN-STEIN N E, CREUSEN R J M, ZIJLSTRA M, et al. Membrane distillation of industrial cooling tower blow down water[J]. Water Resources and Industry, 2016, 14:11-17.
  [13] ZHU H L, WANG H J, WANG F, et al. Preparation and properties of PTFE hollow fiber membranes for desalination through vacuum membrane distillation[J]. Journal of Membrane Science, 2013, 446:145-153.
  [14] LI K L, ZHANG Y, XU L L, et al. Optimizing stretching conditions in fabrication of PTFE hollow fiber membrane for performance improvement in membrane distillation[J]. Journal of Membrane Science, 2018, 550:126-135.
  [15] ZHOU T, YAO Y Y, XIANG R L, et al. Formation and characterization of polytetrafluoroethylene nanofiber membranes for vacuum membrane distillation[J]. Journal of Membrane Science, 2014, 453:402-408.
  [16] HUANG Q L, HUANG Y, XIAO C F, et al. Electrospun ultrafine fibrous PTFE-supported ZnO porous membrane with self-cleaning function for vacuum membrane distillation[J]. Journal of Membrane Science, 2017, 534:73-82.
  [17] GARCÍA-PAYO M C, ESSALHI M, KHAYET M. Effects of PVDF-HFP concentration on membrane distillation performance and structural morphology of hollow fiber membranes[J]. Journal of Membrane Science, 2010, 347:209-219.
  [18] WANG J, ZHENG L B, WU Z J, et al. Fabrication of hydrophobic flat sheet and hollow fiber membranes from PVDF and PVDF-CTFE for membrane distillation[J]. Journal of Membrane Science, 2016, 497:183-193.
  [19] CHEN K K, XIAO C F, HUANG Q L, et al. Study on vacuum membrane distillation (VMD) using FEP hollow fiber membrane[J]. Desalination, 2015, 375:24-32.
  [20] SU C I, SHIH J H, HUANG M, et al. A study of hydrophobic electrospun membrane applied in seawater desalination by membrane distillation[J]. Fibers and Polymers, 2012, 13(6):698-702.
  [21] KE H Z, FELDMAN E, GUZMAN P, et al. Electrospun polystyrene nanofibrous membranes for direct contact membrane distillation[J]. Journal of Membrane Science, 2016, 515:86-97.
  [22] RAY S S, CHEN S S, NGUYEN N C, et al. Poly(vinyl alcohol) incorporated with surfactant based electrospun nanofibrous layer onto polypropylene mat for improved desalination by using membrane distillation[J]. Desalination, 2017, 414:18-27.
  [23] LIU Y, HE J H, YU J Y, et al. Controlling numbers and sizes of beads in electrospun nano-fibers[J]. Polymer International, 2008, 57(4):632-636.
  [24] ESSALHI M, KHAYET M. Self-sustained webs of polyvinylidene fluoride electrospun nano-fibers:Effects of polymer concentration and desalination by direct contact membrane distillation[J]. Journal of Membrane Science, 2014, 454:133-143.
  [25] ESSALHI M, KHAYET M. Self-sustained webs of polyvinylidene fluoride electrospun nanofibers at different electrospinning times:1. Desalination by direct contact membrane distillation[J]. Journal of Membrane Science, 2013, 433:167-179.
  [26] ESSALHI M, KHAYET M. Self-sustained webs of polyvinlidene fluoride electro-spun nanofibers at different electrospinning times:2. Theoretical analysis, polarization effects and thermal efficiency[J]. Journal of Membrane Science, 2013, 433:167-179.
  [27] ADNAN S, HOANG M, WANG H, et al. Commercial PTFE membranes for membrane distillation application:Effect of microstructure and support material[J]. Desalination, 2012, 284:297-308.
  [28] WU H Y, WANG R, FIELD R W. Direct contact membrane distillation:An experimental and analytical investigation of the effect of membrane thickness upon transmembrane flux[J]. Journal of Membrane Science, 2014, 470:257-265.
  [29] SCHOFIELD R W, FANE A G, FELL C J D. Gas and vapour transport through microporous membranes. I. Knudsen-Poiseuille transition[J]. Journal of Membrane Science, 1990, 53(1/2):159-171.
  [30] EBRAHIMI A, KARIMI M, ASHTIANI F Z. Characterization of triple electrospun layers of PVDF for direct contact membrane distillation process[J]. Journal of Polymer Research, 2018, 25:50-59.
  [31] LIAO Y, WANG R, TIAN M, et al. Fabrication of polyvinylidene fluoride (PVDF) nanofiber membranes by electro-spinning for direct contact membrane distillation[J]. Journal of Membrane Science, 2013, 425/426:30-39.
  [32] MA H,BURGER C,HSIAO B S, et al. Ultra-fine cellulose nanofibers:New nano-scale materials for water purification[J]. Journal of Materials Chemistry, 2011(21):7507-7510.
  [33] LALIA B S, GUILLEN-BURRIEZA E, ARAFAT H A, et al. Fabrication and characterization of polyvinylidene fluoride-co-hexafluoropropylene (PVDF-HFP) electrospun membranes for direct contact membrane distillation[J]. Journal of Membrane Science, 2013, 428:104-115.
  [34] SHAULSKY E, NEJATI S, BOO C, et al. Post-fabrication modification of electrospun nanofiber mats with polymer coating for membrane distillation applications[J]. Journal of Membrane Science, 2017, 530:158-165.
  [35] TIJING L D, WOO Y C, SHIM W G, et al. Superhydrophobic nanofiber membrane containing carbon nanotubes for high-performance direct contact membrane distillation[J]. Journal of Membrane Science, 2016, 502:158-170.
  [36] ATTIA H, ALEXANDER S, WRIGHT C J, et al. Superhydrophobic electrospun membrane for heavy metals removal by air gap membrane distillation (AGMD)[J]. Desalination, 2017, 420:318-329.
  [37] HOU D Y, LIN D C, DING C L, et al. Fabrication and characterization of electrospun superhydrophobic PVDFHFP/SiNPs hybrid membrane for membrane distillation[J]. Separation and Purification Technology, 2017,189:82-89
  [38] WOO Y C, TIJING L D, SHIM W G, et al. Water desalination using graphene-enhanced electrospun nanofiber membrane via air gap membrane distillation[J]. Journal of Membrane Science, 2016, 520:99-110.
  [39] PRINCE J A, SINGH G, RANA D, et al. Preparation and characterization of highly hydrophobic poly(vinylidene fluoride)-Clay nanocomposite nanofiber membranes (PVDF-clay NNMs) for desalination using direct contact membrane distillation[J]. Journal of Membrane Science, 2012, 397-398:80-86.
  [40] PRINCE J A, RANA D, SINGH G, et al. Effect of hydrophobic surface modifying macromolecules on differently produced PVDF membranes for direct contact membrane distillation[J]. Chemical Engineering Journal, 2014, 242:387-396.
  [41] JAFARI A, KEBRIA M R S, RAHIMPOUR A, et al. Graphene quantum dots modified polyvinylidenefluride (PVDF) nanofibrous membranes with enhanced performance for air Gap membrane distillation[J]. Chemical Engineering & Processing:Process Intensification, 2018, 126:222-231.
  [42] ATTIA H, OSMAN M S, JOHNSON D J, et al. Modelling of air gap membrane distillation and its application in heavy metals removal[J]. Desalination, 2017, 424:27-36.
  [43] LEE J G, LEE E J, JEONG S, et al. Theoretical modeling and experimental validation of transport and separation properties of carbon nanotube electrospun membrane distillation[J]. Journal of Membrane Science, 2017, 526:395-408.
  [44] LEE E J, AN A K, HE T, et al. Electrospun nanofiber membranes incorporating fluorosilane-coated TiO₂ nanocomposite for direct contact membrane distillation[J]. Journal of Membrane Science, 2016, 520:145-154.
  [45] LALIA B S, GUILLEN E, ARAFAT H A, et al. Nanocrystalline cellulose reinforced PVDF-HFP membranes for membrane distillation application[J]. Desalination, 2014, 332:134-141.
  [46] WOO Y C, CHEN Y, TIJING L D, et al. CF₄ plasma-modified omniphobic electrospun nanofiber membrane for produced water brine treatment by membrane distillation[J]. Journal of Membrane Science, 2017, 529:234-242.
  [47] YANG X, WANG R, SHI L, et al. Performance improvement of PVDF hollow fiber-based membrane distillation process[J]. Journal of Membrane Science, 2011, 369:437-447.
  [48] DENG L, YE H H, LI X, et al. Self-roughened omniphobic coatings on nanofibrous membrane for membrane distillation[J]. Separation and Purification Technology, 2018, 206:14-25.
  [49] Yan K K, Jiao L, Lin S S, et al. Superhydrophobic electrospun nanofiber membrane coated by carbon nanotubes network for membrane distillation[J]. Desalination, 2018, 437:26-33.
  [50] SHAHABADI S M S, RABIEE H, SEYEDI S M, et al. Superhydrophobic dual layer functionalized titanium dioxide/polyvinylidene fluoride-co-hexafluoropropylene (TiO₂/PH) nanofibrous membrane for high flux membrane distillation[J]. Journal of Membrane Science, 2017, 537:140-150.
  [51] AN X C, LIU Z Y, HU Y X. Amphiphobic surface modification of electrospun nanofibrous membranes for anti-wetting performance in membrane distillation[J]. Desalination, 2018, 432:23-31.
  [52] AN A K, GUO J X, LEE E J, et al. PDMS/PVDF hybrid electrospun membrane with superhydrophobic property and drop impact dynamics for dyeing wastewater treatment using membrane distillation[J]. Journal of Membrane Science, 2017, 525:57-67.
  [53] REN L F, XIA F, CHEN V, et al. TiO₂-FTCS modified superhydrophobic PVDF electrospun nanofibrous membrane for desalination by direct contact membrane distillation[J]. Desalination, 2017, 423:1-11.
  [54] HUANG Y X, WANG Z X, HOU D Y, et al. Coaxially electrospun super-amphiphobic silica-based membrane for antisurfactant-wetting membrane distillation. Journal of Membrane Science, 2017, 531:122-128.
  [55] YANG D, LIU X, JIN Y, et al. Electrospinning of poly(dimethylsiloxane)/poly(methyl methacrylate) nanofibrous membrane:Fabrication and application in protein microarrays[J]. Biomacromolecules, 2009, 10(12):3335-3340.
  [56] LIU Y, YANG D, YU T, et al. Incorporation of electrospun nanofibrous PVDF membranes into a microfluidic chip assembled by PDMS and scotch tape for immunoassays[J]. Electrophoresis, 2009, 30:3269-3275.
  [57] REN L F, XIA F, SHAO J H, et al. Experimental investigation of the effect of electrospinning parameters on properties of superhydrophobic PDMS/PMMA membrane and its application in membrane distillation[J]. Desalination, 2017, 404:155-166.
  [58] DONG Z Q, MA X H, XU Z L, et al. Superhydrophobic PVDF-PTFE electrospun nanofibrous membranes for desalination by vacuum membrane distillation[J]. Desalination, 2014, 347:175-183.
  [59] LI K L, HOU D Y, FU C C, et al. Fabrication of PVDF nanofibrous hydrophobic composite membranes reinforced with fabric substrates via electrospinning for membrane distillation desalination[J]. Journal of Environmental Sciences, 2019, 75:277-288.
  [60] ATTIA H, JOHNSON D J, WRIGHT C J, et al. Comparison between dual-layer (superhydrophobic-hydrophobic) and single superhydrophobic layer electrospun membranes for heavy metal recovery by air-gap membrane distillation[J]. Desalination, 2018, 439:31-45.
  [61] SU C L, LU C, CAO H B, et al. Fabrication and post-treatment of nanofibers-covered hollow fiber membranes for membrane distillation[J]. Journal of Membrane Science, 2018, 562:38-46.
  [62] YANG H C, HOU J W, CHEN V, et al. Janus membranes:Exploring duality for advanced separation[J]. Angewandte Chemie International Edition, 2016, 55(43):13398-13407.
  [63] KHAYET M. Membranes and theoretical modeling of membrane distillation:A review[J]. Advances in Colloid and Interface Science, 2011, 164(1/2):56-88.
  [64] ZUO J, CHUNG T S, O'BRIEN G S, et al. Hydrophobic/hydrophilic PVDF/Ultem^® dual-layer hollow fiber membranes with enhanced mechanical properties for vacuum membrane distillation[J]. Journal of Membrane Science, 2017, 523:103-110.
  [65] EDWIE F, TEOH M M, CHUNG T S. Effects of additives on dual-layer hydrophobic hydrophilic PVDF hollow fiber membranes for membrane distillation and continuous performance[J]. Chemical Engineering Science, 2012, 68(1):567-578.
  [66] KHAYET M, GARCÍA-PAYO M C, GARCÍA-FERNÁNDEZ L, et al. Dual-layered electrospun nanofibrous membranes for membrane distillation[J]. Desalination, 2018, 426:174-184.
  [67] WOO Y C, TIJING L D, PARK M J, et al. Electrospun dual-layer nonwoven membrane for desalination by air gap membrane distillation[J]. Desalination, 2017, 403:187-198.
  [68] HOU D Y, DING C L, LI K L, et al. A novel dual-layer composite membrane with underwater-superoleophobic/hydrophobic asymmetric wettability for robust oil-fouling resistance in membrane distillation desalination[J]. Desalination, 2018, 428:240-249.
  [69] WANG K P, HOU D Y, WANG J, et al. Hydrophilic surface coating on hydrophobic PTFE membrane for robust anti-oil-fouling membrane distillation[J]. Applied Surface Science, 2018, 450:57-65.
  [70] HOU D Y, WANG Z X, WANG K P, et al. Composite membrane with electrospun multiscale-textured surface for robust oil-fouling resistance in membrane distillation[J]. Journal of Membrane Science, 2018, 546:179-187.
  [71] PRINCE J A, ANBHARASI V, SHANMUGASUNDARAM T S, et al. Preparation and characterization of novel triple layer hydrophilic-hydrophobic composite membrane for desalination using air gap membrane distillation[J]. Separation and Purification Technology, 2013, 118:598-603.
  [72] SALMÓN I R, JANSSENS R, LUIS P. Mass and heat transfer study in osmotic membrane distillationcrystallization for CO₂ valorization as sodium carbonate[J]. Separation and Purification Technology, 2017, 176:173-183.
  [73] WANG J, SUN X G, YUAN Y, et al. A novel microwave assisted photo-catalytic membrane distillation process for treating the organic wastewater containing inorganic ions[J]. Journal of Water Process Engineering, 2016, 9:1-8.
  [74] LIN S, NEJATI S, BOO C, et al. Omniphobic membrane for robust membrane distillation[J]. Environmental Science &Technology Letters, 2014, 1(11):443-447.
  [75] BOO C, LEE J, ELIMELECH M. Omniphobic polyvinylidene fluoride (PVDF) membrane for desalination of shale gas produced water by membrane distillation[J]. Environmental Science &Technology, 2016, 50(22):12275-12282.