聚酯合成催化技术的研究进展Progress in catalytic technologies for polyester synthesis
王翼嵩,王松林,姜冰雪,李家旭,邓维,史胜斌,LIM Khak Ho,王青月,杨轩,刘平伟,王文俊
摘要(Abstract):
聚酯工业的进步离不开先进的催化技术。本文对聚酯合成催化体系的研究进展进行了评述。着眼于目前占主导的金属催化剂,对锑、钛、锡、锗、铝等催化剂在活性、副反应等方面所开展的金属复合、配体改性、载体负载等工作进行了总结,介绍了有机物、离子液体、酶等非金属催化体系的研究进展,并对促进聚酯合成的电、光、微波等催化辅助技术进行了评述。催化能力强、副反应少、聚合条件温和催化体系的开发有助于聚酯品质的提升,将先进的表征手段、模型研究以及聚酯构效关系规律探索结合到催化体系的研究中,可加速高效聚酯催化技术的研发。
关键词(KeyWords): 聚酯;金属催化剂;缩聚;开环聚合;非金属催化剂
基金项目(Foundation): 山东省重点研发计划(重大科技创新工程)项目(2021CXGC010810);; 化学工程联合国家重点实验室项目(SKL-ChE-22T01);; 浙江大学衢州研究院项目(IZQ2020KJ2004);; 恒逸石化有限公司项目(HY20190101)
作者(Author): 王翼嵩,王松林,姜冰雪,李家旭,邓维,史胜斌,LIM Khak Ho,王青月,杨轩,刘平伟,王文俊
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