生物沼气加压水洗过程厂级动态控制设计与模拟Dynamic Control Design and Simulation of Biogas Pressurized Water Scrubbing Processes
薄翠梅,郭伟,李俊,杨世品,朱文宇,牛超,陆小华
摘要(Abstract):
针对生物质沼气加压水洗提纯净化处理过程,开展厂级动态协同控制方案设计与模拟实验研究。根据生物沼气加压水洗中试装置工艺需求,采用Aspen Plus软件建立其稳态流程模拟系统,并通过对不同工艺操作条件进行稳态模拟获取最佳稳态操作工况。根据工艺要求合理设计厂级动态控制方案,保证沼气提纯率大于97%。通过Aspen Dynamic模块建立其动态流程模拟系统,分别引入沼气进气流量与成分扰动测试系统性能,模拟测试结果和实验运行结果表明,该控制系统具有良好的动态响应性能,而且在多种扰动下CO2的脱除率都大于99.8%,有效抑制各种扰动。
关键词(KeyWords): 生物沼气;提纯净化;加压水洗;动态控制;流程模拟
基金项目(Foundation): 国家自然科学基金(61673205);; 国家重大科研仪器研制项目(21727818);; 材料化学工程国家重点实开放课题基金(KL16-07)
作者(Author): 薄翠梅,郭伟,李俊,杨世品,朱文宇,牛超,陆小华
参考文献(References):
- [1]Ryckebosch E,Drouillon M,Vervaeren H.Techniques for transformation of biogas to biomethane[J].Biomass and Bioenergy,2011,35(5):1633-1645.
- [2]YIN Bing(尹冰),CHEN Lu-ming(陈路明),KONG Qing-ping(孔庆平).Research on purification technology for vehicle biogas(车用沼气提纯净化工艺技术研究)[J].Modern Chemical Industry(现代化工),2009,29(11):28-31.
- [3]ZHEN Feng(甄锋),LI Dong(李东),SUN Yong-ming(孙永明),et al.High value application and purification technology of biogas(沼气高值化利用与净化提纯技术)[J].Environmental Science&Technology(环境科学与技术),2012,35(11):103-108.
- [4]JIN Xiao(金潇),MA Ze-yu(马泽宇),XU Qi-yong(徐期勇).Removal technologies of carbon dioxide in landfill gas and its research advances(填埋气中二氧化碳净化技术及研究进展)[J].Renewable Energy Resources(环境科学与技术),2013,31(1):87-92.
- [5]Alma T,Mayara L S,Saúl B,et al.Photosynthetic biogas upgrading to bio-methane:boosting nutrient recovery via biomass productivity control[J].Algal Research,2016,17:46-52.
- [6]Sun Q,Li H L,Yan J Y,et al.Selection of appropriate biogas upgrading technology:a review of biogas cleaning,upgrading and utilization[J].Renewable and Sustainable Energy Reviews,2015,51:521-532.
- [7]Carios A G,Alírio E R.Biogas to fuel by vacuum pressure swing adsorption I.Behavior of equilibrium and kinetic-based adsorbents[J].Industrial Engineering Chemistry Research,2007,46(13):4595-4605.
- [8]LIU Xiao-rui(刘晓瑞),WANG Yan-ping(汪艳萍),FENG Lei(冯磊),et al.Application of Aspen Plus software in simulating methane decarbonization for vehicle gas(Aspen Plus软件在模拟沼气脱碳制取车用燃气中的应用)[J].Journal of Inner Mongolia University of Technology(内蒙古工业大学学报),2015,34(2):5-10.
- [9]Cozma P,Wukovits W,M?m?lig?I,et al.Modeling and simulation of high pressure water scrubbing technology applied for biogas upgrading[J].Clean Technologies&Environmental Policy,2015,17(2):373-391.
- [10]G?tz M,Koppel W,Reimert R,et al.Potential to optimize scrubbers for biogas cleaning part 1-physical scrubbers[J].ChemieIngenieurTechnik,2011,83(6):858-866.
- [11]Slantela J,Rasi S,Lehtinen J.Landfill gas upgrading with pilot-scale water scrubber:performance assessment with absorption water recycling[J].Applied Energy,2012,92(4):307-314.
- [12]Xiao Y,Yuan H R,Pang Y Z.CO2 removal from biogas by water washing system[J].Chinese Journal of Chemical Engineering,2014,22(8):950-953.
- [13]HAN De-gang(韩德刚),GAO Zhi-di(高执棣),GAO Pan-liang(高盘良).Physical Chemistry(物理化学)[M].Beijing(北京):Higher Education Press(高等教育出版社),2001.