刘迎新,舒慧敏,刘海燕,刘晓爽,曾茂,周阔,魏作君

• 1:浙江工业大学药学院催化加氢研发基地
• 2:浙江大学生物质化工教育部重点实验室浙江大学化学工程与生物工程学院

摘要(Abstract)：

综述了近年来非均相金属催化剂在醇与NH_3还原胺化制备伯胺体系中的应用研究,重点阐述了醇胺化(包括缩合胺化和还原胺化)的反应机理,以及还原胺化制备伯胺所需催化体系的研究进展。醇的脱氢步骤是醇与氨还原胺化制备伯胺反应中的速率控制步骤,不同金属组分由于对NH_3与有机胺的吸附能不同而导致脱氢活性不同。在醇还原胺化制备伯胺的体系中,开发适用于无氢气条件下氢转移胺化的非均相催化剂、选择合适的载体、开发生物质醇合成伯胺的催化技术具有广阔的前景。

关键词(KeyWords)： 醇类物质;还原胺化;伯胺;非均相催化剂

Abstract:

Keywords:

基金项目(Foundation): 国家自然科学基金(21476211);; 浙江省自然科学基金(LY14B060003,LY18B060016)

作者(Author): 刘迎新,舒慧敏,刘海燕,刘晓爽,曾茂,周阔,魏作君

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