掺杂碳材料的制备及其负载贵金属在催化加氢反应中的应用研究进展Preparation of doped carbon materials and their application in catalytic hydrogenation loaded with noble metals
李康,周媛,张群峰,岑亚青,李小年
摘要(Abstract):
贵金属加氢催化剂广泛应用于精细化学品、药物和功能材料的合成中,以改进催化剂制备方法来提高其活性、选择性或稳定性一直是该领域研究热点。而采用掺杂碳材料作为催化剂载体是改善贵金属催化剂加氢性能的一种有效途径。文章系统总结了掺氮、掺硫及其它掺杂碳材料的制备方法,介绍了不同制备方法对碳材料中杂原子含量、物化性质的影响;并概述了掺杂碳载体负载贵金属催化剂在硝基苯类化合物、共轭羰基、苯酚催化加氢以及在加氢脱卤等反应中的应用情况,掺杂催化剂均展现出了优异的催化性能。
关键词(KeyWords): 掺杂碳材料;贵金属;催化剂;催化加氢
基金项目(Foundation): 国家自然科学基金(21476207,21406199,21776258,91534113);; 浙江省科技厅项目(2015C31042)
作者(Author): 李康,周媛,张群峰,岑亚青,李小年
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