环丁砜抽提重石脑油芳烃体系相平衡研究Study on Equilibrium of Sulfolane and Heavy Naphtha Extraction System
王云芳,袁倩,迟正伟
摘要(Abstract):
采用液-液萃取技术脱除重石脑油中的芳烃。常压下,测定了含水量为0.02%、0.3%、0.5%及0.8%的环丁砜与重石脑油在剂油比1:1~5:1及温度为313.15、323.15、333.15、343.15、353.15 K的液-液相平衡数据,全面考察了环丁砜的芳烃抽提性能。结果表明,在环丁砜抽提体系中,轻质芳烃的分配系数与温度呈正比而与剂油比呈反比。环丁砜对轻质芳烃的选择性系数随温度升高而减小,随轻相中芳烃含量的降低而变大。但重质芳烃的分配系数和环丁砜对其选择性系数则随温度和剂油比变化不大。环丁砜含水量为0.5%时,在基本不改变其溶解性能的基础上使其选择性得到了明显改善。
关键词(KeyWords): 环丁砜;芳烃;重石脑油;液-液萃取
基金项目(Foundation): SINOPEC齐鲁分公司研究院科技项目
作者(Author): 王云芳,袁倩,迟正伟
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