姚光艳¹,王琳琳¹,陈小鹏¹,廖丹葵¹,童张法¹,雷福厚²,李鹏飞²

• 1:广西大学 广西石化资源加工及过程强化技术实验室，广西 南宁 530004
• 2:广西民族大学 广西林产化学与工程重点实验室，广西 南宁 530006

摘要(Abstract)：

利用C80型Calvet微量量热仪测定了对伞花烃+β-石竹烯，3-蒈烯+β-石竹烯和3-蒈烯+对伞花烃三个二元体系在298.15 K下的超额焓。三个二元体系的超额焓数据在全浓度范围内均为正值，并且最大值均在摩尔分数x₁=0.5附近。采用Redlich-Kister方程对实验数据进行关联，标准偏差分别为0.2151、0.1773和0.4483 J·mol^-1。结果表明实验所测定的超额焓与关联结果吻合较好。在相同温度下，3-蒈烯+对伞花烃体系的超额焓值均大于含重质松节油组分的对伞花烃+β-石竹烯和3-蒈烯+β-石竹烯体系。

关键词(KeyWords)： β-石竹烯;对伞花烃;3-蒈烯;超额焓;微量量热仪

Abstract:

Keywords:

基金项目(Foundation): 国家自然科学基金（31560241，21566002，21466002）；广西石化资源加工及过程强化技术重点实验室课题基金（2016Z002）。

作者(Author): 姚光艳¹,王琳琳¹,陈小鹏¹,廖丹葵¹,童张法¹,雷福厚²,李鹏飞²

DOI: 10.3969/j.issn.1003-9015.2018.04.005

参考文献(References)：

• [1] Huang M, Sanchez-Moreiras A M, Abel C, et al. The major volatile organic compound emitted from arabidopsis thaliana flowers, the sesquiterpene (E)-β-caryophyllene, is a defense against a bacterial pathogen[J]. New Phytologist, 2012, 193(4):997-1008.
  [2] Ojha S, Javed H, Azimullah S, et al. β-Caryophyllene, a phytocannabinoid attenuates oxidative stress, neuroinflammation, glial activation, and salvages dopaminergic neurons in a rat model of Parkinson disease[J]. Molecular and Cellular Biochemistry, 2016, 418(1):59-70.
  [3] Basha R H, Sankaranarayanan C. β-Caryophyllene, a natural sesquiterpene lactone attenuates hyperglycemia mediated oxidative and inflammatory stress in experimental diabetic rats[J]. Chem-Biological Interactions, 2016, 245(5):50-58.
  [4] Jung J I, Kim E J, Kwon G T, et al. β-Caryophyllene potently inhibits solid tumor growth and lymph node metastasis of B16F10 melanoma cells in high-fat diet-induced obese C57BL/6N mice[J]. Carcinogenesis, 2015, 36(9):1028-1039.
  [5] Sköld M, Karlberg A T, Matura M, et al. The fragrance chemical β-caryophyllene-air oxidation and skin sensitization[J]. Food and Chemical Toxicology, 2006, 44(4):538-545.
  [6] LIU Xiao-yu (刘晓宇), CHEN Xu-bing (陈旭冰), CHEN Guang-yong (陈光勇). Research progress in bioactivity and synthesis of β-caryophyllene and its derivatives (β-石竹烯及其衍生物的生物活性与合成研究进展)[J]. Chemistry and Industry of Forest Products (林产化学与工业), 2012, 1(32):104-110.
  [7] WANG Lin-lin (王琳琳). The catalytic process of intermolecular hydrogen transfer reaction of rosin (松香、松节油及松脂中分子间氢转移催化反应的研究)[D]. Nanning (南宁):Guangxi University (广西大学), 2007.
  [8] Retajczyk M, Wróblewska A. The isomerization of limonene over the Ti-SBA-15 catalyst-the influence of reaction time, temperature, and catalyst content[J]. Catalysts, 2017, 7(9):273.
  [9] Sun L X, Liao D K, Yang Z Y, et al. Measurement and correlation of (vapor + liquid) equilibrium data for {α-pinene +p-cymene +(S)-(-)-limonene} ternary system at atmospheric pressure[J]. Journal of Chemical Thermodynamics, 2013, 58:416-421.
  [10] XU Xiao-qin (徐晓琴), LIAO Dan-kui (廖丹葵), LI Li-shuo (李立硕), et al. Determination and correlation of atmospheric VLE data of α-pinene +β-pinene +p-cymene (α-蒎烯+β-蒎烯+对伞花烃常压汽液平衡测定与关联)[J]. Journal of Chemical Industry and Engineering (化工学报), 2007, 58(12):2970-2974.
  [11] Banina O A, Sudarikov D V, Frolova L L, et al. Carane amino alcohols as organocatalysts in asymmetric aldol reaction of isatin with acetone[J]. Russian Chemical Bulletin, 2017, 66(2):293-296.
  [12] Yan Z L, Wang C L, Hou L H, et al. Extraction of oleoresin from Dao-Kou roasted chicken flavor spice blends using supercritical carbon dioxide[J]. Food Analytical Methods, 2017, 10(4):900-909.
  [13] Torregiani E, Lorier S, Sagratini G, et al. Comparative analysis of the volatile profile of 20 commercial samples of truffles, truffle sauces, and truffle-flavored oils by using HS-SPME-GC-MS[J]. Food Analytical Methods, 2017, 10(6):1857-1869.
  [14] Lee H R, Lee S C, Lee D H, et al. Identification of the aggregation-sex pheromone produced by male monochamus saltuarius, a major insect vector of the pine wood nematode[J]. Journal of Chemical Ecology, 2017, 43(7):670-678.
  [15] Alparslan Y, Baygar T. Effect of chitosan film coating combined with orange peel essential oil on the shelf life of deep water pink shrimp[J]. Food and Bioprocess Technology, 2017, 10(5):842-853.
  [16] MA Pei-sheng (马沛生), XIA Shu-qian (夏淑倩), WU Xiao-xiang (吴小香). The experimental determination and correlation of excess enthalpies of binary systems of cyclohexanone with different alcohols (环己酮-醇二元系统超额焓测定与关联的研究)[J]. Acta Physico-Chimica Sinica (物理化学学报), 2002, 18(7):644-648.
  [17] RUAN Fu-xian (阮付贤), CHE Jin-jie (车锦楷), HU Jing (胡静), et al. Vapor-liquid equilibrium of α-pinene-pinnae-longifolene systems and their excess Gibbs free energy and excess enthalpy (α-蒎烯-蒎烷-长叶烯体系汽液平衡及其过量Gibbs自由能与超额焓)[J]. Journal of Chemical Engineering of Chinese Universities (高校化学工程学报), 2015, 29(6):1306-1322.
  [18] Berlin A, Comlli F. Excess molar enthalpies of binary mixtures containing pine resins in the range 288.15~313.15 K, and at atmospheric pressure:use of the extended cell model of prigogine[J]. Thermochimica Acta, 2001, 373(1):45-51.
  [19] LIAO Dan-kui (廖丹葵), MENG Xue-lin (孟学林), WU Xiang-hong (武向红), et al. Determination of excess enthalpies for binary systems of α-pinene +p-cymene and β-pinene +p-cymene (α-蒎烯+对伞花烃和β-蒎烯+对伞花烃二元体系超额焓的测定)[J]. Acta Physico-Chimica Sinica (物理化学学报), 2006, 22(11):1419-1422.
  [20] SUN Li-xia (孙丽霞). Measurement and calculation of vapor-liquid equilibrium and excess enthalpy data for main constituents in turpentine oil system (松节油体系主要成分的汽液平衡与超额焓的测定与计算)[D]. Nanning (南宁):Guangxi University (广西大学), 2013.
  [21] Speight J G. Lange's handbook of chemistry[M]. 16th ed. New York:Mc Graw-Hill, 2005.
  [22] Haynes W M, Lide D R, Bruno T J. CRC handbook of chemistry and physics[M]. 95th ed, Boca Raton:CRC Press, 2014.
  [23] MA Pei-sheng (马沛生). Experimental handbook of physical properties of organic compounds-carbon, hydrogen, oxygen, halogen section (有机化合物实验物性数据手册-含碳、氢、氧、卤部分)[M]. Beijing (北京):Chemical Industry Press (化学工业出版社), 2006.
  [24] Ribeiro A, Bernado-Gil M G. Densities and refractive indices of components of pine resin[J]. Journal of Chemical Engineering Data, 1990, 35(2):204-206.
  [25] Letyanina I, Tsvetov N, Zvereva I, et al. Excess molar enthalpies for binary mixtures of n-propanol, acetic acid, and n-propyl acetate at 313.15 K and atmospheric pressure[J]. Fluid Phase Equilibria, 2014, 381(15):77-82.
  [26] Calvet E, Prat H. Microcalorimétrie:applications physico-chimiques et biologiques[M]. Paris:Masson et Cie, 1956.
  [27] McGlashan M L, Hugill J A. The vapor pressure from 451 K to the critical temperature, and the critical temperature and critical pressure, of cyclohexane[J]. Journal of Chemical Thermodynamics, 1978, 10(1):95-100.
  [28] Gruszkiewicz M S, Sipowska J T, Qtt J B, et al. Excess enthalpies for (ethane + ethene) at the temperatures (273.15, 298.15, 323.15, 348.15, and 363.15) K and the pressures (5, 7.5, 10, 12.5, and 15) MPa[J]. Journal of Chemical Thermodynamics, 1995, 27(5):507-524.