潘华淳,骆一周,贾颖娜,孙晨,雷乐成,杨彬

• 1:浙江大学化学与生物工程学院
• 2:浙江省生态环境科学设计研究院

摘要(Abstract)：

针对流动电极材料在分离有机物/无机阴离子时选择性低、吸附容量有限及循环稳定性差的问题，通过原位生长双金属ZIF(Co/Zn)于聚吡咯(PPy)导电网络上并高温碳化(900℃)的策略，制备了碳化改性ZIF(Co/Zn)@PPy复合材料，并将其作为流动电极用于电容去离子(FCDI)系统，处理含头孢类抗生素的高盐废水。结果表明：碳化后材料相对于碳化前具有更丰富的介孔结构与更优异的电化学性能，电荷传输性能明显改善，电荷效率由74.06%提高至95.50%；对NaCl的吸附容量提升77%，有机/无机阴离子分离因子达13 635，且20次循环后性能保持率超97%。该碳化改性策略显著提升了ZIF@PPy流动电极材料的性能，为开发高效、高选择性分离回收高盐有机废水中有机物的FCDI技术提供了新材料基础和理论支撑。

关键词(KeyWords)： 流动电极材料;ZIF(Co/Zn)@PPy;碳化;电化学性能;吸附

Abstract:

Keywords:

基金项目(Foundation): 浙江省领雁研发计划项目(2023C03140)

作者(Author): 潘华淳,骆一周,贾颖娜,孙晨,雷乐成,杨彬

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