膜控制氧化反应器中丁烯氧化脱氢的研究Study on a Controllable Oxidative Dehydrogenation of Butene in a Novel Inorganic Membrane Reactor
李志华,刘长厚,王连军,葛善海
摘要(Abstract)：
在气体均布的无机膜控制氧化反应器上进行了丁烯氧化脱氢制丁二烯反应，并将其与固定床方式反应的实验结果进行了对比，结果表明在实验范围内膜反应器比传统的固定床反应更为有效。建立了描述控制氧化膜反应器操作性能的数学模型，并将模型求解值与实验值对比，吻合良好。
关键词(KeyWords)： 膜反应器;控制氧化;均布;丁烯氧化脱氢
基金项目(Foundation): 国家自然科学基金!(No.29776005)
作者(Author): 李志华,刘长厚,王连军,葛善海
参考文献(References)：
- [1] LI Qin-hua (李亲华). Technology advances in oxydehydrogenation process for producing butadiene in China(我国丁烯氧化脱氢制丁二烯技术进展)[J]. Petrochemical Technology (石油化工), 1990, 19(3): 183-190.
- [2] WU Zhi-nan (吴指南). Fundamental Organic Chemical Process (Second Edition) (基本有机化工工艺学(第二版))[M], Beijing (北京):Chemical Engineering Press(化学工业出版社), 1989.
- [3] Tellez C, Menendz M, Santamaria J. Oxidative dehydrogenation of butene using membrane reactors[J]. AIChE Journal, 1997, 43(3): 777-784.
- [4] XING Jun-hang (刑军航). Preparation of Aluminium Oxide Membrane, Gas Permeation and its Application in Catalytic Dehydrogenation (氧化铝膜的制备.气体渗透及在催化脱氢中的应用)[D]. Dalian (大连): Dalian University of Technology(大连理工大学),1995.
- [5] BO Zhi-jun (柏志军), DU Ying-chun (杜迎春), ZHANG Ji-rui (张吉瑞). Kinetics of oxidative dehydrogenation of butene to butadiene over B-O2 catalyst by sequential experiment design (用序惯实验设计法研究B-O2催化剂上丁烯氧化脱氢动力学)[J]. Jouranl of Chemical Industry and Engineering (化工学报), 1994, 45(2): 247-252.
- [6] DING Xue-jia (丁雪加), XIAO Di (肖弟), WANG Xiao-lai (王小来). The redox model of kinetics for the oxidative dehydrogenation of butene over the ferrite (丁烯氧化脱氢动力学的氧化还原模型)[J]. Journal of Molecular Catalysis(分子催化), 1988, 2(1): 25-30.