氯化氢、水二元体系的汽液平衡VAPOR LIQUID EQUILIBRIUM of HYDROCHLORIDE—WATER BINARY SYSTEM
陆小华,王延儒,时钧
摘要(Abstract):
用双循环型平衡釜测定了101.3kPa(1atm)下盐酸体系的汽液平衡关系,所得数据与具有代表性的诸文献值作了比较和评价。将Pitzer(1980)方程简化成单参数形式,通过并联盐酸中水的活度系数求得参数,然后推算其中氯化氢的活度系数及汽液平衡组成,结果与本文实测数据相当一致,19组沸点值的平均偏差为0.046K,15组汽相摩尔分率的平均偏差为0.0020。
关键词(KeyWords):
基金项目(Foundation):
作者(Author): 陆小华,王延儒,时钧
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