窦晓冬,刘国杰

• 1:华东理工大学化学系
• 2:华东理工大学化学系 上海200237
• 3:上海200237

摘要(Abstract)：

利用实验测得的液体的热压力系数,修正原始van der Waals模型中的排斥体积,得到了一个适用于高密度流体的推广的van der Waals压缩因子。将它与Redlich和Kwong提出的吸引项相结合,建立了一个流体状态方程。用某些有代表性的超临界流体的pVT数据检验,结果表明,其对体积、压力和逸度系数的计算准确度可与CS-RK方程相媲美。

关键词(KeyWords)： 热压力系数;压缩因子;状态方程;超临界流体

Abstract:

Keywords:

基金项目(Foundation):

作者(Author): 窦晓冬,刘国杰

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