项斌,高扬,史津晖,何敏焕

• 1:浙江工业大学化学工程与材料学院

摘要(Abstract)：

以负载氯化亚铜为催化剂,研究了苯乙烯和四氯化碳加成反应的动力学,为工业反应过程的开发和操作提供了理论依据。在本实验条件下,催化剂的粒径为10 8～10 7m,内扩散影响可以忽略。当搅拌速度大于210 r min 1时,外扩散影响基本消除,反应进入动力学控制区。系统地测定了65～75℃下的反应动力学数据。依据自由基加成反应机理和单活性位吸附的假设,建立了动力学模型,rA=K[CA][CB]+k1[CB]。对实验数据进行非线性拟合,得到反应动力学模型参数。计算得到其控制步骤解离吸附的反应活化能为1.11×105kJ mol 1。动力学模型与实验数据吻合较好,在实验范围内可信度较高。

关键词(KeyWords)： 苯乙烯;四氯化碳;反应动力学

Abstract:

Keywords:

基金项目(Foundation):

作者(Author): 项斌,高扬,史津晖,何敏焕

参考文献(References)：

• [1]SUN Cun-zhong(孙存中),LIU Bin(刘冰),LIU Huan-shu(刘焕书).Approach to industrialization of cinnamic acid synthesizedfrom styrene and carbon tetrachloride(苯乙烯-四氯化碳合成肉桂酸工业化问题的探讨)[J].Modern Chemical Industry(现代化工),2000,20(15):27-28.
• [2]LIN Ming-yang(李明阳),WANG Yong-qiang(王永强).Studies on the synthesis of cinnamic acid(肉桂酸的合成方法研究)[J].ACTA Scientiarum Naturalium Universitatis Jilinensis(吉林大学自然科学学报),1989,(2):131-133.
• [3]REN Li-guo(任立国),GAO Wen-yi(高文艺),ZHAO Chong-feng(赵崇峰).Synthesis of cinnamic acid from styrene and carbontetrachloride(苯乙烯和四氯化碳合成肉桂酸)[J].Journal of Liaoning University of Petroleum&Chemical Technology(辽宁石油化工大学学报),2005,25(1):9-12.
• [4]CHEN Yu-sheng(陈雨生).The application and synthesis of Cinnamic Acid(肉桂酸的用途与合成)[J].Zhejiang ChemicalIndustry(浙江化工),1992,23(l):18-20.
• [5]Ihl Gabriele Dr,Roscher Guenter Dr,Mayer Norbert Dr.Process for the preparation of cinnamic Acid:DE,3743616[P].1988-08-04.
• [6]Telschow Jeffrey E.Preparation of cinnamic acid:US,4571432[P].1986-02-18.
• [7]Hoberg,Heinz.New synthesis of cinnamic acid and its derivatives[J].Organonmet Chem,1986,307(2):38-40.
• [8]XU Xin(徐昕),LüChan-jun(吕禅君).Study on the analytical method of intermediate1,3,3,3-tetrachloropropylphenyl in thesynthesis of cinnamic acid(肉桂酸合成反应中间体1,3,3,3-四氯丙基苯的分析方法研究)[J].Zhejiang Chemical Industry(浙江化工),2004,(11):24-25.
• [9]Mears D E.Test for transport limitations in experimental catalytic reactors[J].Ind Eng Chem Process Des Devpt,1971,10(4):541-547.
• [10]LI Zhao-hui(李朝辉),PU Zhen(卜真),CHEN Ri-zhi(陈日志),et al.Intrinsic kinetics of ammoximation of acetone with hydrogenperoxide catalyzed by TS-1.(TS-1催化丙酮氨氧化制丙酮肟)[J].J Chem Eng of Chinese Univ(高校化学工程学报),2009,23(3):423-427.
• [11]YUN Kui-hong(恽魁宏),GAO Hong-bin(高鸿宾),REN Ze-zhong(任责忠).Advanced Organic Chemistry(高等有机化学)[M].Beijing(北京):Higher Education Press(高等教育出版社),1986:334.
• [12]Carey F A,Sundberg R J.Advanced Organic Chemistry.A,Volume-Structure and Mechanism(高等有机化学A卷-结构与机理)[M].Beijing(北京):People’s Education Press(人民教育出版社),1983:442-443.
• [13]LIU Chen-xue(刘春雪),MI Zhen-tao(米镇涛),WANG Li(王莅).Intrinsic kinetics study on hydrogenation of2-amylanthraquinone(2-戊基蒽醌氢化本征动力学研究)[J].J Chem Eng of Chinese Univ(高校化学工程学报),2007,21(3):530-533.