尹红,黄海平,陈志荣,袁慎峰

• 1:浙江大学化学工程与生物工程学院

摘要(Abstract)：

以Cu Cl2-Fe Cl3混合金属盐水溶液为催化剂,以正己醇为溶剂进行2,3,6-三甲基苯酚(TMP)多相氧化反应。通过副产物2,2',3,3',5,5'-六甲基-4,4'-联苯二酚(IP)和中间产物4-氯-2,3,6-三甲基苯酚(Cl TMP)生成情况推测Cu Cl2和Fe Cl3催化反应网络。研究结果表明副产物IP主要在反应初始阶段生成,Cl?通过促进中间产物Cl TMP生成进而抑制副反应。反应温度为358.15 K,Cu Cl2使用量7.57%(mol),Fe Cl3使用量3.78%(mol),反应进行8 h,目的产物即2,3,5-三甲基-1,4-对苯醌(TMQ)收率为80.66%。

关键词(KeyWords)： 2,3,6-三甲基苯酚;2,3,5-三甲基-1,4-对苯醌;氧化反应;催化反应网络

Abstract:

Keywords:

基金项目(Foundation): 浙江省重点科技创新团队计划项目(2011R50007);; 浙江省公益技术应用研究计划(2013C31091)

作者(Author): 尹红,黄海平,陈志荣,袁慎峰

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