反相微乳液制备AgCl/PMMA复合胶乳及其抗菌性能Preparation of Ag Cl/PMMA Latex via W/O Microemulsion and its Antibacterial Activity
陈甜甜,李娜,祝方琦,孙志轩,吴礼光
摘要(Abstract):
以聚乙二醇辛基苯基醚(OP)为表面活性剂,甲基丙烯酸甲酯(MMA)为油相构筑的反相微乳液合成纳米Ag Cl粒子,然后通过微乳液聚合制备Ag Cl/PMMA复合胶乳。利用紫外-可见吸收光谱(UV-vis)和透射电镜(TEM)研究微乳液中表面活性剂浓度(cop)、水相中盐浓度(csalt)对纳米Ag Cl粒子的形成及形貌影响,结果发现合成的Ag Cl粒子近似球状,粒径在5 nm左右;在反相微乳液中随cop、csalt的增加,形成的纳米Ag Cl粒子数增多、平均粒径有所减小。Ag Cl/PMMA复合胶乳对大肠杆菌表现出明显的抗菌活性。通过反相微乳液及其聚合技术制备包含有纳米Ag Cl的复合胶乳,方法简便、易于放大,所制备的Ag Cl/PMMA复合胶乳作为抗菌剂具有良好的应用前景。
关键词(KeyWords): 聚乙二醇辛基苯基醚;反相微乳液;Ag Cl纳米粒子;Ag Cl/PMMA复合胶乳;抗菌性能
基金项目(Foundation): 国家自然科学基金(20876144,21076190,21376218)
作者(Author): 陈甜甜,李娜,祝方琦,孙志轩,吴礼光
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