潘薪羽^1,2,赵丽^1,2,马空军²,王强^1,2

• 1:新疆大学 理化测试中心，新疆 乌鲁木齐 830046
• 2:新疆大学 化学化工学院，煤炭清洁转化与化工过程自治区重点实验室，新疆 乌鲁木齐 830046

摘要(Abstract)：

采用反气相色谱法（IGC）研究四种咪唑基离子液体在温度333.15、343.15、353.15、363.15、373.15 K时的溶解度参数，同时，采用汉森三维溶解度参数软件（HSPiP）模拟四种咪唑基离子液体在333.15 K时的三维溶解度参数。333.15 K时，IGC测得的四种咪唑基离子液体的溶解度参数分别为δ_{t（EMIMOTF）}=23.51（J·cm^-3）^1/2，δ_{t（BMIMOTF）}=23.39（J·cm^-3）^1/2，δ_{t（HMIMOTF）}=22.79（J·cm^-3）^1/2，δ_{t（OMIMOTF）}=22.31（J·cm^-3）^1/2，333.15 K时，HSPiP得出的四种咪唑基离子液体的溶解度参数分别为δ_{t（EMIMOTF）}=24.28（J·cm^-3）^1/2，δ_{t（BMIMOTF）}=23.26（J·cm^-3）^1/2，δ_{t（HMIMOTF）}=22.79（J·cm^-3）^1/2，δ_{t（OMIMOTF）}=22.08（J·cm^-3）^1/2，IGC与HSPiP得出的溶解度参数值一致。根据HSPiP可以模拟出离子液体的三维溶解度参数球，并依据三维溶解度参数球可以快速准确地选取离子液体的良溶剂或混合溶剂。研究结果为离子液体的热力学性质研究及其溶剂选择等应用提供了参考。

关键词(KeyWords)： 离子液体;溶解度参数;反气相色谱;汉森三维溶解度参数软件

Abstract:

Keywords:

基金项目(Foundation): 国家自然科学基金（21366029，21566036）。

作者(Author): 潘薪羽^1,2,赵丽^1,2,马空军²,王强^1,2

DOI: 10.3969/j.issn.1003-9015.2018.01.005

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