姚光艳,王琳琳,陈小鹏,廖丹葵,童张法,雷福厚,李鹏飞

• 1:广西大学广西石化资源加工及过程强化技术实验室
• 2:广西民族大学广西林产化学与工程重点实验室

摘要(Abstract)：

利用C80型Calvet微量量热仪测定了对伞花烃+β-石竹烯,3-蒈烯+β-石竹烯和3-蒈烯+对伞花烃三个二元体系在298.15 K下的超额焓。三个二元体系的超额焓数据在全浓度范围内均为正值,并且最大值均在摩尔分数x1=0.5附近。采用Redlich-Kister方程对实验数据进行关联,标准偏差分别为0.2151、0.1773和0.4483 J·mol~(-1)。结果表明实验所测定的超额焓与关联结果吻合较好。在相同温度下,3-蒈烯+对伞花烃体系的超额焓值均大于含重质松节油组分的对伞花烃+β-石竹烯和3-蒈烯+β-石竹烯体系。

关键词(KeyWords)： β-石竹烯;对伞花烃;3-蒈烯;超额焓;微量量热仪

Abstract:

Keywords:

基金项目(Foundation): 国家自然科学基金(31560241,21566002,21466002);; 广西石化资源加工及过程强化技术重点实验室课题基金(2016Z002)

作者(Author): 姚光艳,王琳琳,陈小鹏,廖丹葵,童张法,雷福厚,李鹏飞

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