碳酸二甲酯-草酸二甲酯二元常压汽液相平衡Vapor-Liquid Equilibria for the Binary System of Dimethyl Carbonate(1)-Dimethyl Oxalate(2)
马新宾,李振花,王保伟,许根慧
摘要(Abstract):
用气相单循环的玻璃平衡釜测定了碳酸二甲酯-草酸二甲酯二元系统的常压汽液相平衡数据,用积分法对其进行了热力学一致性检验。回归得到了草酸二甲酯的Antoine方程参数。用Wilson活度系数方程对实验数据进行了关联, 取得了较好的结果。
关键词(KeyWords): 碳酸二甲酯;汽液相平衡;草酸二甲酯;活度系数
基金项目(Foundation): 云南省省院省校合作项目资助
作者(Author): 马新宾,李振花,王保伟,许根慧
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