谢波,张震乾,丁建宁,方必军,李坚

• 1:常州大学 材料科学与工程学院，江苏省光伏科学与工程协同创新中心，江苏 常州 213164

摘要(Abstract)：

通过反相细乳液聚合合成了含有硫酸镉（CdSO₄）的聚丙烯酰胺（PAM）乳胶粒子，并通过吸收硫化钠（Na₂S）细乳液制备了硫化镉-聚丙烯酰胺（CdS-PAM）纳米杂化粒子。研究了CdS-PAM杂化粒子形成过程中乳胶粒子吸收细乳液液滴吸收时间和温度的影响因素；考察了水合CdSO₄/Na₂S用量对乳胶粒子吸收液滴过程以及对CdS-PAM纳米杂化粒子的影响，并测定了CdS-PAM杂化粒子的光催化性能。结果表明：随着硫酸镉用量的增加，乳胶粒子吸收硫化钠细乳液液滴能力减弱。以0.100 g/0.094 g水合CdSO₄/Na₂S制备的CdS-PAM杂化粒子具有较好的光催化性能。至此，采用反相细乳液成功制备出了具有光降解性能的CdS-PAM纳米杂化粒子。

关键词(KeyWords)： 反相细乳液;硫化镉;有机-无机;杂化粒子;光催化

Abstract:

Keywords:

基金项目(Foundation): 国家自然科学基金（51577015）。

作者(Author): 谢波,张震乾,丁建宁,方必军,李坚

DOI: 10.3969/j.issn.1003-9015.2019.01.025

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