生物基N,S双掺杂荧光碳点的制备及其应用Synthesis and application of bio-based N, S co-doped fluorescent carbon dots
许利娜,杨小华,丁海阳,李梅,李守海,夏建陵
摘要(Abstract):
为了扩展造纸废液中的木质素磺酸钠的应用,以木质素磺酸钠和半胱氨酸为原料通过绿色的一步水热反应制备N, S双掺杂碳点,利用紫外可见光谱、荧光光谱和透射电镜等表征了碳点的光学性能、结构和对金属离子的选择性检测性能,结果表明制备的N,S双掺杂碳点可以识别Fe~(3+),在0.5~100μmol×L~(-1),Fe~(3+)的浓度与制备的碳点的荧光猝灭强度有良好的线性关系(R2=0.995)。将制备的碳点用于实际水样,结果表明可实现水样中3价铁离子的检测。此荧光探针原料成本低廉,制备绿色简便,在检测领域和生物质资源的高附加值应用领域有着很好的应用前景。
关键词(KeyWords): 杂原子掺杂;碳量子点;荧光探针;木质素;选择性吸附
基金项目(Foundation): 江苏省生物质能源与材料重点实验室基金(JSBEM-S-201807);; 中央级公益性科研院所基本科研业务费专项资金(CAFYBB2017QA016)
作者(Author): 许利娜,杨小华,丁海阳,李梅,李守海,夏建陵
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