王东辉,刘硕,侯海亮,郑丰平,汪汉卿,应安国,李桂芹

• 1:台州学院医药化工学院
• 2:天津大学化工学院
• 3:浙江建业化工股份有限公司
• 4:江西仁明医药化工有限公司

摘要(Abstract)：

制备了一种以三乙烯二胺(DABCO)为基础的碱性离子液体[DHC3dabco][BF4],在超声环境下以芳醛、丙二腈和5,5-二甲基-1,3-环己二酮为原料,该离子液体为催化剂,在水相中合成四氢苯并[b]吡喃类衍生物。应用该催化剂反应条件温和、反应时间短、操作简便、收率高。在简单活性亚甲基化合物的基础上探讨了其他活性亚甲基化合物与芳香醛及双甲酮的反应。

关键词(KeyWords)： DABCO;四氢苯并[b]吡喃;活性亚甲基化合物;水相;超声

Abstract:

Keywords:

基金项目(Foundation): 国家自然科学基金项目(21106090);; 浙江省低碳脂肪胺工程技术研究中心开放基金项目(2012E10033);; 台州学院校立学生科研项目(13XS26)

作者(Author): 王东辉,刘硕,侯海亮,郑丰平,汪汉卿,应安国,李桂芹

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