5-羟甲基糠醛选择性加氢制备2,5-二甲基呋喃研究进展Review on 2,5-Dimethylfuran Synthesis via Selective Hydrogenation of 5-Hydroxymethylfufural
刘迎新,曾茂,楼炯涛,刘晓爽,舒慧敏,魏作君
摘要(Abstract):
2,5-二甲基呋喃是21世纪最有发展前景的生物质能源之一。由生物质方法制备2,5-二甲基呋喃是目前研究的热点。文章综述了近年来由碳水化合物和5-羟甲基糠醛制备2,5-二甲基呋喃的研究成果,重点讨论了反应机理、催化反应体系和常用溶剂等方面的进展。目前该反应体系中使用的催化剂以负载的单金属Ru、Pd、Ni,双金属催化剂以及金属-氧化态金属催化剂为主;常用溶剂包括四氢呋喃和醇类。从生物质一步制备2,5-二甲基呋喃有利于降低反应成本,提高碳水化合物的利用率,是未来值得研究的方向。
关键词(KeyWords): 2,5-二甲基呋喃;5-羟甲基糠醛;选择性加氢;反应机理;金属催化剂;生物质
基金项目(Foundation): 国家自然科学基金(21476211);; 浙江省自然科学基金(LY14B060003,LY18B060016)
作者(Author): 刘迎新,曾茂,楼炯涛,刘晓爽,舒慧敏,魏作君
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