电解质溶液的粘性电解质模型及其应用SEM Model for Electrolyte Solution and its Application
陈学玺,刘洪来
摘要(Abstract)：
在平均球近似（ＭＳＡ）理论的基础上引入离子缔合项和短程作用力项，建立了粘性电解质模型（ＳＥＭ）。离子间导入粘性屏蔽作用，阴离子取Ｐａｕｌｉｎｇ晶体直径，阳离子直径和能量参数由参数估计求得。对１６种碱金属卤化物水溶液的活度系数进行模拟计算，与实验数据比较，误差普遍小于３％，满足工程设计的需要。
关键词(KeyWords)： 电解质溶液;缔合;热力学性质;活度系数
基金项目(Foundation):
作者(Author): 陈学玺,刘洪来
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