丁醇异构物塔的模拟研究与优化改造Simulation and Optimization of a Butanol Isomer Column
李治水,聂增来,庞栓林,王松,谢智勇,李云辉
摘要(Abstract):
以天津渤化永利化工股份有限公司#2丁辛醇装置中小板间距的丁醇异构物塔进料负荷提升为研究目标,结合实际生产装置调试结果,采用Aspen及KG-TOWER软件对丁醇异构物塔进行流程模拟及水力学计算,并根据研究结果采用VG固阀和弧形溢流堰对丁醇异构物塔进行优化改造,使丁醇异构物塔的进料负荷提高了20%上。本研究对提升丁辛醇装置中丁醇异构物塔的进料负荷具有重要的指导意义,为小板间距精馏塔的设计及优化提供了工程依据和研究基础。
关键词(KeyWords): 丁醇异构物塔;计算模拟;塔板效率;液相返混;优化改造
基金项目(Foundation): 天津市科技兴海项目(KJXH2013-04)
作者(Author): 李治水,聂增来,庞栓林,王松,谢智勇,李云辉
参考文献(References):
- [1]Tudor R,Ashley M.Enhancement of industrial hydroformylation processes by the adoption of rhodium-based catalyst:Part I[J].Platinum Metals Review,2007,51(3):116-126.
- [2]SHI Jin-yan(史瑾燕),ZOU Pei-liang(邹佩良),ZHANG Jun-xian(张俊先).The development of low pressure synthesis of butanol and octanol with carbonyl(低压羰基法生产丁辛醇工艺技术进展)[J].Chemical Intermediates(化工中间体),2008(7):15-16.
- [3]Lee S Y,Park J H,Jang S H,et al.Fermentative butanol production by Clostridia[J].Biotechnology and Bioengineering,2008,101(2):209-228.
- [4]Jin C,Yao M,Liu H,et al.Progress in the production and application of n-butanol as a biofuel[J].Renewable and Sustainable Energy Reviews,2011,15(8):4080-4106.
- [5]ZHANG Xia(张霞),LI Hong-wei(李红伟),MA Xiao-jian(马晓建).Optimization of enzymatic hydrolysis conditions of steam-exploded corn stover(汽爆玉米秸秆发酵丁醇的酶解工艺优化)[J].Journal of Chemical Engineering of Chinese Universities(高校化学工程学报),2014,28(4):934-938.
- [6]SUN Qiang(孙强),GUO Xu-qiang(郭绪强),LIU Ai-xian(刘爱贤),et al.Separating propane and propylene from the vent gas of butyl octanol unit via hydrate formation(水合物法分离丁辛醇弛放气中的丙烷丙烯)[J].Journal of Chemical Engineering of Chinese Universities(高校化学工程学报),2011,25(1):18-23.
- [7]Kister H Z.Distillation troubleshooting[M].Hoboken:John Wiley&Sons,2011.
- [8]Kister H Z.Distillation operation[M].New York:Mc Graw-Hill,Inc,1990.
- [9]Lanzhou Petroleum Machinery Research Institute(兰州石油机械研究所).Modern column technology(现代塔器技术)[M].Beijing(北京):China Petrochemical Press(中国石化出版社),2005.