潘翠,郑涛,陈怡露,魏荣卿,张家宏,刘晓宁

• 1:南京工业大学药学院
• 2:南京工业大学生物能源研究所
• 3:南京工业大学生物与制药工程学院

摘要(Abstract)：

经氯乙酰聚苯乙烯微球(PS-acyl-Cl)的ATRP接枝聚合,制备了具有触角状聚苯乙烯链的聚苯乙烯树脂(PS-g-LPS),该树脂可快速、高效磺化,经磺化条件的优化,得到一新型的触角状聚苯乙烯磺酸树脂(v HP-SPS-Cat),对v HP-SPS-Cat进行了FT-IR、元素分析、光学显微镜观察及催化酯化。结果表明,v HP-SPS-Cat可克服试剂的物理扩散的阻碍,用于小分子酯或生物柴油的催化合成,而达到高效均相催化的效果。

关键词(KeyWords)： ATRP;触角状聚苯乙烯磺酸树脂;氯乙酰聚苯乙烯;磺化;催化酯化

Abstract:

Keywords:

基金项目(Foundation): “973”项目(2013CB733504);; “863”项目(2012AA021203)

作者(Author): 潘翠,郑涛,陈怡露,魏荣卿,张家宏,刘晓宁

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